Safety data sheet product name synonyms emergency telephone number section 1. The light naphtha surplus and the potential impact of tier. Adsorption isotherms have been determined in a pressure vessel. Ep1284281b1 ep02022116a ep02022116a ep1284281b1 ep 1284281 b1 ep1284281 b1 ep 1284281b1 ep 02022116 a ep02022116 a ep 02022116a ep 02022116 a ep02022116 a ep 02022116a ep 1284281 b1 ep1284281 b1 ep 1284281b1 authority ep european patent office prior art keywords fuel composition synthetic naphtha naphtha cloud point prior art date 19990406 legal status the legal status is an assumption and. Naphtha is incompatible with strong oxidizing agents such as nitric acid.
Design parameters for a hydro desulfurization hds unit. Not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. Raw naphtha, sour naphtha, wild naphtha, heartcut naphtha, crude naphtha, coker naphtha, lsr naphtha, light straight run naphtha, unstabilized naphtha. Sulfur species was not found at all in the products of gasoline and kerosene regardless of their yields and process conditions. Hydrodesulfurization hydrodesulfurization hds or hydrotreating is a catalytic chemical process widely used to remove sulfur compounds from refined petroleum products such as gasoline or petrol, jet fuel, diesel fuel, and fuel oils. Please do not confuse naphtha poisoning for added potency when using it as a solvent to make phoenix tears. A gasoline blending components production system useful for producing both aromatics and gasoline blending components from naphtha. Since it is the second lightest product of all the refinery yields produced, it is obtained immediately after liquefied petroleum gas lpg during the first distillation process.
Any sulfur and nitrogen present in the hydrocracking feedstock are, to a large extent, also hydrogenated and form gaseous hydrogen sulfide h 2 s and ammonia nh 3, which are subsequently removed. Sulfur converted to hydrogen sulfide h2s added hydrogen breaks carbon. Removal of sulfur compounds from naphtha solutions using. This has made its downstream processing quite challenging. Some of the hydrogen sulphidehydrogen mixture is recycled back to the reactor to utilize the unreacted hydrogen, using a compressor. Naphtha petroleum, light hydrocracked registration. Do not move along or opposite to the direction of wind.
This invention relates to the hydroprocessing of naphtha with removal of mercaptan from product. Us patent for process for producing diesel patent patent. Lastly a hydrocracked fuel was used, containing a low level of mono, di and tri aromatics, for comparison with the hydrogenated fuel. Us7799210b2 process for removing sulfur from naphtha. The carbon species in the light and middle distillates were much the same regardless of their yields and process conditions. A major portion of the desulfurized naphtha is then heated to 800 to. Box 2844, 150 6th avenue southwest calgary alberta t2p 3e3 canada emergency telephone number. Naphtha full boiling range naphtha, heavy naphtha, light naphtha, paraffinic naphtha, petroleum distillatenaphtha untreated process streams, such as the following may contain hydogen sulfide. The remaining 40% was composed of mercaptanes and alkyl sulfides. Am0553 page 1 lco upgrading a novel approach for greater added value and improved returns vasant p. The naphtha hydrotreating process is also important to pretreat naphtha for downstream units, like paraffin isomerization and catalytic reforming, where severe specifications are required and catalysts used are very sensitive to impurities. Advances in naphtha steam cracking december 2005 this pep report is designed to help clients better understand the technology changes that. Naphtha is a product which is obtained through the dry distillation of organic substances such as shale or crude oil in a refinery.
Pretreatment of the samples by open column chromatography and silver nitrate treatment were introduced to assign sulfur species. Uops coker naphtha hydrotreating process removes contaminants from 100% coker naphtha or can be used for blends containing coker naphtha and other naphtha streams. Hydrocracked kerosene this is a highquality jet fuel or diesel blendstock with low sulfur and high smoke point. The chemical reactions are similar to those in the sulfuric acid process, but it is possible to use higher temperatures between 24 and 46 c, or 75 to 115 f, thus avoiding the need for refrigeration. Analysis of sulfur compounds in straightrun naphtha and.
Hydrocracking is a catalytic cracking process assisted by the presence of an elevated partial pressure of hydrogen. Naphtha hydrotreater oil refinery naphtha hydrotreater. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of c6 through c12, and boiling in the range of approximately 65c to 230c 148f to 446f. Design parameters for a hydro desulfurization hds unit for petroleum naphtha at 3500 barrels per day. Charring may occur followed by ignition of unreacted material and nearby combustibles. Longterm exposure may cause effects to specific organs, such as to the liver, kidneys, blood, nervous system, and skin. A complex combination of hydrocarbons from distillation of the products from a hydrocracking process.
Thiophene and its alkyl derivatives constituted about 60% of the total sulfur compounds in the naphtha fraction. Material safety data sheet naphtha page 2 of 14 2 14 drowsiness, headache, and similar narcotic symptoms, but no longterm effects. Manufacturer or suppliers details suncor energy inc. Process work of a naphtha hydrotreating unit proses industri. Naptha generated from hydrocracker is having less then 5. The process has since evolved to feed vacuum gas oil vgo, coker gas oils, and deasphalted oils to produce distillates, primarily ultralowsulfur diesel ulsd, kerosene, and naphtha for use as. The naphtha cut from the atmospheric distillation unit is sent to the naphtha hydrotreater to remove sulfur and nitrogen compounds. Naphtha with a small aromatic content has a slight odor, but the aromatics increase the solvent power of the naphtha and there is no need to remove aromatics unless odorfree naphtha is. There is a continuing need, therefore, for improved methods of producing more diesel from hydrocarbon feedstocks than gasoline.
Hydrodesulfurization hds is a catalytic chemical process widely used to remove sulfur s from natural gas and from refined petroleum products, such as gasoline or petrol, jet fuel, kerosene, diesel fuel, and fuel oils. Naphtha kerosene distillate ago lvgo hvgo vacuum residuum cat distillates gas oil hydrotreating dao isomerate gas alkyl feed alkylate polymerization naphtha gases butanes lpg reformate naphtha fuel oil bottoms distillates distillate hydrotreating cat naphtha cycle oils sda bottoms coker naphtha heavy coker gas oil light coker gas oil sulfur. Dmso addition to naphtha very low in sulfur content, furnace operation for both maximum ethylene and. Purpose of the naphtha hydrotreating unit is to remove sulphur and nitrogen compounds. Naphtha material safety data sheet complex mixture of. In the gas oil boiling range 210340 two groups of sulfur compounds, namely, alkyl benzothiophenes and alkyl dibenzothiophenes were present. Coker naphtha typically contains up to 20 times more sulfur and high levels of nitrogen than straightrun naphtha. All these products have a very low content of sulfur and other contaminants. Sulfurcontaining compounds in straightrun naphtha and catalyticcracked gasoline were analyzed quantitatively using gas chromatography with a sulfur chemiluminescence detector. Coker naphtha contaminants typically, coker naphtha contains 1020 times more sulphur and higher amounts of. However, in straight run materials, significant quantities of aliphatic sulfur compounds and further higher boiling benzothiophenes are also expected. The hydrocracker is particularly valuable in a refinery that is trying to maximize diesel production and reduce residual fuel oil. The purpose of removing the sulfur, and creating products such as ultralowsulfur diesel, is to reduce the sulfur dioxide so. Such methods must ensure that the diesel product meets increasingly stringent product requirements.
The objective is to reduce sulfur and nitrogen contents less than 0. Capital and operating costs of the integrated plant is lower than two separate plants. This investigation indicated that activated carbon is superior to zeolite x at such high temperatures. The hydrocracker yields a high volume of kerosene and light gasoil of good quality high cetane and low sulfur. A threestep process of removing sulfur from naphtha feeds. Us patent for method for cracking a hydrocarbon feedstock. Light hydrocrackate this is a lowquality gasoline blendstock with low octane but also low sulfur. Charge, isomerate, low sulfur gas, light straight run naphtha lsr, naphtha, naphtha splitter bottoms, naphtha splitter overhead, naphtha to east, nhds charge, nht charge, nht debutanizer bottoms, nsu bottoms, nsu overhead, overhead. This is particularly the case for naphtha hydrotreaters, since the properties of coker naphtha are very different from those of straightrun sr naphtha. Lco upgrading a novel approach for greater added value. Correlations of emissions species with aromatic content are less significant. Naphtha cut which is obtained from crude is typically defined, as c5140 in a refiners lingo but the end point of naphtha that is found in modern refineries can be as high as 180 degc.
Sulfur species that convert in hydrocracking are from the frontend of bitumen pitch. June 20, 2012 status message from a friend of mine was donated some phoenix tears oil from an understandably unnamed source. The major products from hydrocracking are jet fuel and diesel, but low sulphur naphtha fractions and lpg are also produced. The naphtha hydro treating unit uses a cobaltmolybdenum catalyst to remove sulfur by converting it to hydrogen sulfide that is removed along with unreacted hydrogen. In a mercaptan recombination case study where sr naphtha was processed at 8. Compositional analysis of deasphalted oils from arabian. Mc gehee uop llc des plaines, illinois, usa introduction lco in the clean fuels refinery as refiners plan to meet regulations for clean fuels, one of the many considerations they face is. Nht naphtha hydrotreating unit is a functional to perform the decomposition components of sulfur, oxygen, nitrogen, and metal compounds. The steps include a first hydrotreating step, a mercaptan removal agent and an adsorbent containing a reactive metal on an inorganic support. The naphtha hydrotreating unit uses a cobaltmolybdenum catalyst to remove sulfur by converting it to hydrogen sulfide that is removed along with unreacted hydrogen. But you have to look for a good adsorbent in the guard as life of the adsorbent is also an issue. The result is that the hydrocracking products are essentially free of sulfur and nitrogen impurities and consist mostly of paraffinic hydrocarbons. Treatment with the mercaptan removal agent lowers the sulfur content to 30 wppm. The major sulfur species in middle distillates is aromatic compounds, predominantly benzothiophenes and dibenzothiophenes.
The present conditions are effective for hds of the hydrocracked products. Light naphtha, heavy naphtha, reformer feed, platformer feed, hydrodesulfurized naphtha, hydrotreated naphtha, er57. The major components were naphtha c5c10, kerosene c7c15, and gas oil c14c23. Distillate hydrotreating hydrotreating processes aim at the removal of impurities such as sulfur and nitrogen from distillate fuelsnaphtha, kerosene, and dieselby treating the feed with hydrogen at elevated temperature and pressure in the presence of a catalyst. The location of the guard should be made based on a number of issues. Recovery of hydrofluoric acid is accomplished by distillation. It consists predominantly of saturated hydrocarbons having carbon numbers predominantly in the range of c4 through c10, and boiling in the range of. The light naphtha surplus and the potential impact of tier 3 sulfur page 2 with the production surge of light tight oil lto in the u. Naphtha feedstock is hydrotreated and hydrocracked. The present invention relates to a process for cracking a hydrocarbon feedstock in a steam cracker unit, comprising the following steps of. The production system includes a light hydrocracked naphtha splitter, a medium hydrocracked naphtha splitter, a naphtha hydrotreater, an isomerization unit, a continuous catalytic reformer and aromatics complex. I am currently working in diesel hydrotreater plant. The products of this process are saturated hydrocarbons. In contrast, the kind and quantity of sulfur species in the gas oil were dependent on the reaction conditions.
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